Author Affiliations
Abstract
1 MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001 Heilongjiang, People’s Republic of China
2 School of Materials Science and Engineering, East China Jiaotong University, Nanchang, 330013 Jiangxi, People’s Republic of China
3 School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150001 Heilongjiang, People’s Republic of China
Although covalent organic frameworks (COFs) with high π-conjugation have recently exhibited great prospects in perovskite solar cells (PSCs), their further application in PSCs is still hindered by face-to-face stacking and aggregation issues. Herein, metal–organic framework (MOF-808) is selected as an ideal platform for the in situ homogeneous growth of a COF to construct a core–shell MOF@COF nanoparticle, which could effectively inhibit COF stacking and aggregation. The synergistic intrinsic mechanisms induced by the MOF@COF nanoparticles for reinforcing intrinsic stability and mitigating lead leakage in PSCs have been explored. The complementary utilization of π-conjugated skeletons and nanopores could optimize the crystallization of large-grained perovskite films and eliminate defects. The resulting PSCs achieve an impressive power conversion efficiency of 23.61% with superior open circuit voltage (1.20 V) and maintained approximately 90% of the original power conversion efficiency after 2000 h (30–50% RH and 25–30 °C). Benefiting from the synergistic effects of the in situ chemical fixation and adsorption abilities of the MOF@COF nanoparticles, the amount of lead leakage from unpackaged PSCs soaked in water (< 5 ppm) satisfies the laboratory assessment required for the Resource Conservation and Recovery Act Regulation.
Nano-Micro Letters
2024, 16(1): 171
实现双盖格-米勒(Geiger-Müller,GM)计数管量程扩展测量的关键是双GM计数管量程切换控制技术,该技术可使探测器自动选择合适量程的GM计数管进行测量。但是由于两种不同测量量程的GM计数管存在性能差异,传统的将测量量程分成两个区域的方法会导致双GM计数管在量程交叠区域内线性拟合度较低。为了提高双GM计数管在测量量程交叠区域内的线性度,提出了一种量程控制测量方法。该方法将测量范围划分为低量程、中量程以及高量程三个区间,并且还可在三个测量量程之间进行快速自动切换,其中在中量程测量中,分别将两个GM计数管获得的数据进行加权处理。采用241Am源和60Co源进行双GM计数管探测器电路测试,初步测试结果表明:设计的双GM计数管探测器可实现在三个测量量程区间内快速自动切换。同时,双GM计数管在剂量率交叠区域1 000~10 000 μGy·h-1中的线性拟合度得到改进,使得在251~25 130 μGy·h-1的测试范围内,双GM计数管的测量线性度提高至0.999 1,有效地提高了双GM计数管的整体测量线性度。
双GM计数管 量程切换 交叠区域 Dual Geiger Miller counter tubes Range switch Overlapping region
强激光与粒子束
2024, 36(4): 043011
1 咸阳师范学院离子束与光物理实验室,陕西 咸阳 712000
2 西安交通大学物理学院,陕西 西安 710049
3 中国科学院近代物理研究所,甘肃 兰州 730000
用动能为1360 keV的129Xeq+(q=17,20,23,25,27)高电荷态离子分别入射到金属Al和Ti固体靶表面,测量高电荷离子与表面相互作用过程中离子俘获表面电子完成中性化所形成的激发态Xe原子和低电离态Xe离子退激辐射的近红外光谱线(800~1700 nm),以及靶原子被离化激发、退激辐射的光谱线。实验结果表明:高电荷态离子入射金属表面的过程中,携带的势能在飞秒量级的时间内沉积到靶表面,使靶原子离化激发,较强的库仑势能可使靶原子形成高离化态和复杂的电子组态、退激辐射光谱线。随着入射离子的电荷态增加,测量谱线的强度增大,该变化趋势与入射离子的势能随电荷增加的变化趋势大体一致,说明经典过垒模型在近玻尔速度能区是成立的。
原子与分子物理学 高电荷态离子 经典过垒模型 禁戒跃迁 近红外光谱
光通信研究
2024, 50(1): 23016201
天津工业大学纺织科学与工程学院 天津 300387
探究高能辐照下环氧树脂损伤降解机理,以提高环氧树脂在辐照环境下的稳定性。本研究将石墨烯量子点(GQDs)作为自由基清除剂,减缓γ辐照环境下环氧树脂的降解,并研究了GQDs对环氧树脂抗辐照性能的影响机制。结果表明:经过辐照后环氧树脂力学性能下降49%,玻璃化转变温度下降4.4 ℃;石墨烯量子点/环氧树脂(GQDs/EP)复合材料的力学性能下降35%,玻璃化转变温度下降2.2 ℃;GQDs的引入使得辐照后的GQDs/EP复合材料产生的自由基含量显著低于纯树脂自由基的含量。GQDs纳米颗粒也改善了辐照前后环氧树脂的力学性能和热学稳定性。因此,GQDs纳米颗粒可以作为自由基清除剂,有效地提高环氧树脂的辐照稳定性。GQDs清除自由基机制与sp2碳域和表面的官能团有密切相关。本研究为提高环氧树脂在γ射线辐照下的稳定性提供了新的思路和方法。
环氧树脂 纳米颗粒 抗辐照性能 Epoxy resin Nanomaterials Radiation resistance 辐射研究与辐射工艺学报
2024, 42(1): 010205
Author Affiliations
Abstract
Shanghai Institute of Laser Plasma, CAEP, Shanghai 201899, People’s Republic of China
The use of broadband laser technology is a novel approach for inhibiting processes related to laser plasma interactions (LPIs). In this study, several preliminary experiments into broadband-laser-driven LPIs are carried out using a newly established hundreds-of-joules broadband second-harmonic-generation laser facility. Through direct comparison with LPI results for a traditional narrowband laser, the actual LPI-suppression effect of the broadband laser is shown. The broadband laser had a clear suppressive effect on both back-stimulated Raman scattering and back-stimulated Brillouin scattering at laser intensities below 1 × 1015 W cm-2. An abnormal hot-electron phenomenon is also investigated, using targets of different thicknesses.
Matter and Radiation at Extremes
2024, 9(1): 015602